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Radiation curing technology
Advantages of uv curing
The uv curing process
UV curing steps
 

THE UV CURING PROCESS

 

  The UV curing process entails the use of a UV lamp that drives the light onto the surface covered with a liquid formulation containing the photoinitiator. The photoinitiator generates radicals that convert the formulation into a solid, cured film. The formulation is based on monomers, acting also as reactive diluents, and oligomers. The monomers and oligomers are generally derivatives of acrylate/methacrylate, containing polyurethanes, polyesters or polyethers. The type of oligomer characterises the properties of the final product.

The photoinitiator is the key of the curing process because it starts polymerisation and cross-linking reaction. Under UV irradiation the photoinitiator fragments into free radicals that are the reactive species for the polymerisation of unsaturated moieties.

 

 

The curing process develops through the following steps:

  • Generation of the reactive species (radicals)
  • Initiation
  • Propagation/chain transfer
  • Termination
 
 



The mechanism of radical generation occurs through two possible pathways, depending on the chemical characteristics of the photoinitiator: Norrish Type I (a-cleavage) and Norrish Type II (intermolecular hydrogen transfer). The a-cleavage photoinitiators generate radicals by direct absorption of light through a unimolecular process; the hydrogen transfer photoinitiators entail a bimolecular process requiring the presence of a hydrogen donating source for the generation of free radicals.

   
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